Generation and reaction of carbenes from α-oxacyclo-N-aziridinyl imines - A new method for ring expansion of cyclic ethers

DOI: 10.1039/CC9960000909

Source and publish data:

Chemical Communications p. 909 - 910 (1996)

Update date:2022-08-17

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Authors:

Kim, Sunggak

Yoon, Joo-Yong

Cho, Chang Mook

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Article abstract of DOI:10.1039/CC9960000909

α-Oxetanyl-N-aziridinyl imines undergo ring expansion on heating to afford dihydrofurans via alkylidenecarbenes, whereas heating α-tetrahydrofuranyl and α-tetrahydropyranyl N-aziridinyl imines affords the ring expanded cyclic enol ethers via alkyl carbene

Full text of DOI:10.1039/CC9960000909

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