Helvetica Chimica Acta p. 2173 - 2178 (1980)
Update date:2022-08-11
Topics:
Bartok, Mihaly
Felfoeldi, Karoly
Bozoki-Bartok, Gizella
The transformation of isomeric 1,3-Chloroalcohols 1-4, with cyclohexane skeleton, were studied in aqueous solution containing barium hydroxide.As regards the compounds with cis-configuration, 1 gives the oxetane 5 by intramolecular nucleophilic substitution, while 3 gives the unsatured alcohols 7 and 8 by elimination.In the case of the trans-isomers 2 and 4, fragmentation reactions occur in competition with elimination.The main reaction kinetic parameters of the transformations of the four compounds were determined.
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Doi:10.1021/jacs.6b05389
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