Catalysis Communications p. 23 - 28 (2017)
Update date:2022-08-11
Topics:
Xue, Benjing
Sun, Hongjian
Niu, Qingfen
Li, Xiaoyan
Fuhr, Olaf
Fenske, Dieter
The hydrosilylation of aldehydes and ketones under mild conditions with hydrido thiophenolato iron(II) complexes [cis–Fe(H)(SAr)(PMe3)4] (1–4) as catalysts is reported using (EtO)3SiH as an efficient reducing agent in the yields up to 95%. Among them complex 1 is the best catalyst. Complex 1 could also be used as catalyst to reduce the α,β-unsaturated carbonyl compounds selectively to the α,β-unsaturated alcohols in high yields.
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