Catalysis Communications p. 6 - 11 (2017)
Update date:2022-08-24
Topics:
Chen, Sheng-Chun
Lu, Sheng-Nan
Tian, Feng
Li, Nan
Qian, Han-Yu
Cui, Ai-Jun
He, Ming-Yang
Chen, Qun
A new Cu(II)-based metal-organic framework {[Cu2(1,2-BDC)2(Fbtx)2]·3H2O}n (denoted as Cu-FMOF, CCDC-1519440, 1,2-BDC?=?1,2-benzenedicarboxylate, Fbtx?=?1,4-bis(1,2,4-triazole-1-ylmethyl)-2,3,5,6-tetrafluorobenenze) was hydrothermally synthesized and structurally characterized. The Cu-FMOF exhibits a 3D 4-connected coordination framework with the extremely rare (65·8)-hxg-d-4-P2/c topology. Using air as the oxidant, the crystalline Cu-FMOF could be used as a highly efficient heterogeneous catalyst for the TEMPO-assisted oxidation of alcohols to aldehydes. Furthermore, the Cu-FMOF catalyst could be easily recovered and reused for several times without a significant loss of catalytic activity or structural deterioration.
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