Poly(9,9′-spirobifluorene-manganese porphyrin): A new catalytic material for oxidation of alkenes by iodobenzene diacetate and iodosylbenzene

DOI: 10.1039/b301717f

Source and publish data:

Chemical Communications p. 1104 - 1105 (2003)

Update date:2022-08-10

Topics:

Authors:

Poriel, Cyril

Ferrand, Yann

Le Maux, Paul

Raul-Berthelot, Joelle

Simonneaux, Gerard

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Article abstract of DOI:10.1039/b301717f

Anodic oxidation of tetraspirobifluorene-manganese porphyrin lead to the coating of the working electrode by insoluble electroactive poly(9,9′-spirobifluorene-manganese porphyrin) films for which electrochemical behaviour and physicochemical properties are described; these polymeric materials are able to catalyze the heterogeneous epoxidation of styrene with iodobenzene diacetate and iodosylbenzene.

Full text of DOI:10.1039/b301717f

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