Organic Mass Spectrometry p. 995 - 999 (1992)
Update date:2022-08-17
Topics:
Eichinger, Peter C. H.
Bowie, John H.
The gas-phase Smiles reaction of RC6H4O(CH2)nO(1-) (n = 2 or 3) is an ipso rearrangement which is strongly influenced by the nature of the substituent R.Electron-withdrawing groups enhance the rearrangement.When the substituent R is halogen or Me, and occupies the ortho position, ortho cyclization competes with the Smiles rearrangement.
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