Journal of the Chemical Society. Chemical communications p. 1691 - 1692 (1993)
Update date:2022-08-11
Topics:
Baciocchi, Enrico
Bernini, Roberta
Lanzalunga, Osvaldo
The one electron transfer oxidation of 2,2-dimethyl-2-silaindane by K5CoIIIW12O40 leads, in a slow step, to a radical cation which then undergoes fast C-Si bond cleavage, thus indicating that the rate of this cleavage is not significantly affected by the orientation of the C-Si bond with respect to the aromatic system.
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