Hypervalent Iodine Oxidation of Enol Silyl Ethers using Boron Trifluoride Etherate. A Direct Route to Aryl Hydroxymethyl Ketones

DOI: 10.1055/s-1985-31394

Source and publish data:

Synthesis p. 943 - 944 (1985)

Update date:2022-08-11

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Authors:

Moriarty, Robert M.

Prakash, Om

Duncan, Michael P.

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Article abstract of DOI:10.1055/s-1985-31394

Enol silyl ethers of acetophenones and acetylpyridines are oxidized to hydroxymethyl aryl ketones (ω-hydroxyacetophenones) and hydroxyacetylpyridines, respectively, using the system iodosobenzene/boron trifluoride etherate/water.

Full text of DOI:10.1055/s-1985-31394

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