Journal of the Chemical Society. Chemical communications p. 1857 - 1858 (1995)
Update date:2022-08-11
Topics:
Begue, Jean-Pierre
Bonnet-Delpon, Daniele
Percy, Jonathan M.
Rock, Michael H.
Wilkes, Robin D.
Chlorodifluoromethyl ketones reacted with diazomethane to afford epoxides in high yield; upon treatment with butyllithium, the epoxides underwent efficient ring opening to afford 3,3-difluoro-2-alkyl-alken-1-ols, suitable substrates for sigmatropic rearra
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