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Diastereoselective Reactions of δ-Siloxyallylzirconium Reagents with Aldehydes

DOI: 10.1016/0040-4039(95)01418-H

Source and publish data:

Tetrahedron Letters p. 7137 - 7140 (1995)

Update date:2022-08-29

Topics:

Authors:

Clark, Andrew J.Clark, Andrew J.

Kasujee, IsmailKasujee, Ismail

Peacock, Joanne L.Peacock, Joanne L.

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Article abstract of DOI:10.1016/0040-4039(95)01418-H

δ-Siloxyallylzirconium reagent (2) was produced by reaction of the TBDMS protected derivative (6) with zirconocene butene complex "Cp2Zr".Treatment of the δ-siloxyallylzirconium reagent (2) with various aldehydes provided predominantly anti-homoallylic alcohols.

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Full text of DOI:10.1016/0040-4039(95)01418-H

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