Journal of Organic Chemistry p. 1333 - 1336 (1983)
Update date:2022-08-17
Topics:
Kikukawa, Kiyoshi
Kono, Kiyoshi
Wada, Fumio
Matsuda, Tsutomu
Arenediazonium salts are effectively functionalized with a methyl or vinyl group by palladium-catalyzed coupling with organotin compounds in acetonitrile at room temperature.Fairly good yields were obtained irrespective of the nature of a substituent on the aromatic ring, including a nitro group.Transformation of the diazonium group can proceed chemoselectively even in the presence of halogen substituents.
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