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Substituent effects in the rhodium catalyzed hydroformylation of olefins using bis(diarylphosphino)methylamino ligands

DOI: 10.1016/S0040-4039(97)01345-2

Source and publish data:

Tetrahedron Letters p. 5967 - 5970 (1997)

Update date:2022-08-17

Topics:

Authors:

Reetz, Manfred T.Reetz, Manfred T.

Waldvogel, Siegfried R.Waldvogel, Siegfried R.

Goddard, RichardGoddard, Richard

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Article abstract of DOI:10.1016/S0040-4039(97)01345-2

Rhodium-complexes of bis(diarylphosphino)methylamino ligands RN(CH2PPh2)2 are active catalysts in the hydroformylation of 1-octene and 2-vinylnaphthalene, regioselectivity (n/iso-ratio) and catalyst activity (TOF) depending upon the nature of the para-substituent in the N-aryl moiety (R = C6H5, p-CF3-C6H4, P-NMe2-C6H4).

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Full text of DOI:10.1016/S0040-4039(97)01345-2

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