Tetrahedron Letters p. 5967 - 5970 (1997)
Update date:2022-08-17
Topics:
Reetz, Manfred T.
Waldvogel, Siegfried R.
Goddard, Richard
Rhodium-complexes of bis(diarylphosphino)methylamino ligands RN(CH2PPh2)2 are active catalysts in the hydroformylation of 1-octene and 2-vinylnaphthalene, regioselectivity (n/iso-ratio) and catalyst activity (TOF) depending upon the nature of the para-substituent in the N-aryl moiety (R = C6H5, p-CF3-C6H4, P-NMe2-C6H4).
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