Journal of the Chemical Society. Chemical communications p. 1435 - 1436 (1989)
Update date:2022-08-16
Topics:
Sato, Masayuki
Orii, Chisato
Sakaki, Jun-ichi
Kaneko, Chikara
Chiral spirocyclic dioxinones (S)-(6) and (S)-(7) have been synthesized from (-)-menthone and used in Diels-Alder reactions with cyclopentadiene; remarkable diastereofacial selectivity (isopropyl side) and endo preference observed in these reactions have offered a new methodology for asymmetric Diels-Alder reactions.
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