Electrogenerated Zinc as the Catalyst in the Allylation of Carbonyl Compounds. Direct Synthesis of α-Methylene-γ-Lactones

DOI: 10.1016/S0040-4020(01)87246-X

Source and publish data:

Tetrahedron p. 7723 - 7732 (1993)

Update date:2022-08-12

Topics:

Authors:

Rollin, Y.

Derien, S.

Dunach, E.

Gebehenne, C.

Perichon, J.

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Article abstract of DOI:10.1016/S0040-4020(01)87246-X

The electroreduction of a catalytic amount of ZnBr2 in acetonitrile provided a active Zn*, able to catalyze the reductive coupling of allyl bromides and chlorides with carbonyl compounds with high regioselectivity.Substituted α-methylene γ-lactones were o

Full text of DOI:10.1016/S0040-4020(01)87246-X

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