BIS(1-TRIFLUOROMETHYL-2,2,2-TRIFLUOROETHOXY)TRIPHENYLPHOSPHORANE. A NEW ROUTE TO TRIFLUOROMETHYLATED HETEROCYCLES

DOI: 10.1246/cl.1983.167

Source and publish data:

Chemistry Letters p. 167 - 168 (1983)

Update date:2022-08-15

Topics:

Authors:

Kubota, Toshio

Yamamoto, Kazuhiro

Tanaka, Tatsuo

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Article abstract of DOI:10.1246/cl.1983.167

Bis(1-trifluoromethyl-2,2,2-trifluoroethoxy)triphenylphosphorane(1) readily reacted with anilines to form N-hexafluoroisopropylated products (2).By the dehydrofluorination of 2,2-arylamino-1,1,3,3,3-pentafluoropropenes(3) were obtained.Furthermore, when a

Full text of DOI:10.1246/cl.1983.167

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