ACCEPTED MANUSCRIPT
Table 3, entry 122: Beige solid. 1H NMR (CDCl3, 400 MHz) δ 7.38 (d, J = 8.0 Hz, 2H,
H-arom), 7.09 (t, J = 8.0 Hz, 2H, H-arom), 6.85 (d, J = 8.0 Hz, 2H, H-arom), 6.67 (t,
J = 4.0, 8.0 Hz, 1H, H-arom), 6.59 (d, J = 8.0 Hz, 2H, H-arom), 4.81 (brs, 1H, NH),
4.70 (d, J = 24.0 Hz, 1H, CH), 4.15-4.07 (m, 2H, OCH2CH3), 3.99-3.89 (m, 1H,
OCH2CH3), 3.75-3.66 (m, 4H, OCH2CH3+OCH3), 1.27 (t, J = 4.0, 8.0 Hz, 3H,
OCH2CH3), 1.13 (t, J = 4.0, 8.0 Hz, 3H, OCH2CH3) ppm. 13C NMR (101 MHz, CDCl3)
δ 159.39 (d, J = 3.03 Hz, Cq), 146,46 (d, J = 15.15 Hz, Cq), 129.22 (s, CH-arom),
129.04 (d, J = 6.06 Hz, CH-arom), 127.78 (d, J = 3.03 Hz, Cq), 118.42 (s, CH-arom),
114.14 (d, J = 3.03 Hz, CH-arom),113.97 (s, CH-arom), 63.32 (d, J = 4.04 Hz,
OCH2CH3), 63.25 (d, J = 4.04 Hz, OCH2CH3), 55.45 (d, J = 153.52 Hz, CH), 55.30 (s,
31
OCH3), 16.53 (d, J = 6.06 Hz, OCH2CH3), 16.35 (d, J = 6.06 Hz, OCH2CH3) ppm. P
NMR (162 MHz, CDCl3) δ 23.29 ppm. Anal. Calcd. for C18H24NO4P: C, 61.88; H, 6.92;
N, 4.01. Found: C, 61.02; H, 6.89; N, 3.94.
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Table 3, entry 321: Beige solid. H NMR (CDCl3, 400 MHz) δ: 7.45 (dd, J = 4.0 Hz,
J = 8.0 Hz, 2H, H-arom), 7.11 (t, J = 8.0 Hz, 2H, H-arom), 7.02 (t, J = 8.0 Hz, 2H,
H-arom), 6.70 (d, J = 4.0, 8.0 Hz, 1H, H-arom), 6.57 (d, J = 8.0 Hz, 2H, H-arom), 4.74
(d, J = 24.0 Hz, 1H, CH), 4.47 (brs, 1H, NH), 4.14-4.08 (m, 4H, OCH2CH3), 3.98-3.94
(m, 1H, OCH2CH3), 3.78-3.72 (m, 1H, OCH2CH3), 1.28 (t, J = 8.0 Hz, 3H, OCH2CH3),
1.14 (t, J = 4.0, 8.0 Hz, 3H, OCH2CH3) ppm. 13C NMR (101 MHz, CDCl3) δ 163.74 (d,
J = 4.04 Hz, Cq), 161.32 (t, J = 8.08, 4.04 Hz, Cq), 146.20 (d, J = 15.15 Hz, Cq),
131.75 (t, J = 3.03 Hz, Cq), 129.53 (t, J = 3.03, 6.06 Hz, CH-arom), 129.37 (d,
J = 15.15 Hz, CH-arom), 118.67 (s, CH-arom), 115.77 (d, J = 3.03 Hz, CH-arom),
115.55 (d, J = 2.02 Hz, CH-arom), 113.93 (s, CH-arom), 63.46 (d, J = 7.07 Hz,
OCH2CH3), 63.34 (s, OCH2CH3), 55.46 (d, J = 152.51 Hz, CH), 16.52 (d, J = 5.05 Hz,
OCH2CH3), 16.32 (d, J = 6.06 Hz, OCH2CH3) ppm. 31P NMR (162 MHz, CDCl3)
δ 22.93 ppm. Anal. Calcd. for C17H21FNO3P: C, 60.53; H, 6.27; N, 4.15. Found: C,
59.98; H, 6.11; N, 4.03.
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Table 3, entry 4: Beige solid. H NMR (CDCl3, 400 MHz) δ 7.24 (t, J = 8.0 Hz, 2H,
H-arom), 6.83-6.78 (m, 3H, H-arom), 4.50 (d, J = 16.0 Hz, 1H, CH), 4.30 (s, 2H, Cp),
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4.30-3.90 (m, 11H, Cp, OCH2CH3) 1.21-1.14 (m, 6H, OCH2CH3) ppm. C NMR (101
MHz, CDCl3) δ 147.23 (d, J = 6.06 Hz, Cq), 129.30 (s, CH-arom), 118.30 (s,
CH-arom), 113.55 (s, CH-arom), 85.33 (d, J = 7.07 Hz, Cq), 68.69 (s, CH, Cp), 68.03
(s, CH, Cp), 67.67 (s, CH, Cp), 65.93 (d, J = 2.02 Hz, CH, Cp), 63.13 (d, J = 7.07 Hz,
OCH2CH3), 62.55 (d, J = 7.07 Hz, OCH2CH3), 51.77 (d, J = 162.61 Hz, CH), 16.45 (d,
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