Crown Thioether Chemistry. Synthesis and Structural Investigation of 1,5,9-Trithiacyclododecane (Trithia-12-crown-3) and its Copper(II) Chloride Adduct

DOI: 10.1039/DT9880000093

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 93 - 96 (1988)

Update date:2022-08-17

Topics:

Authors:

Rawle, Simon C.

Admans, Gary A.

Cooper, Stephen R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9880000093

1,5,9-Trithiacyclododecane (L¹) (trithia-12-crown-3) adopts a square conformation similar to that of cyclododecane, with one sulphur atom at a corner and two in side positions.Reaction with copper(II) chloride yields an adduct, 1)2Cl2>, that has been characterized by X-ray diffraction.Each copper ion occupies a centre of inversion and has idealized octahedral microsymmetry, with thioether groups at distances of 2.447(1) and 3.050(1) Angstroem.The conformation adopted by the macrocycle is virtually identical to that adopted by the free ligand, which suggests that its conformation is determined by intrinsic factors rather than packing forces.

Full text of DOI:10.1039/DT9880000093

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:3,3'-THIODIPROPANOL

Cas No:10595-09-2

R&D Labs maybe for 10595-09-2

Anhui Biochem United Pharmaceutical Co., Ltd.

Contact:0086 551 5167062 / 5228268

Address:No. 30 Hongfeng Road, Hi-Tech Development Zone, Hefei (230088), China
shanghai hekang chemical co.ltd

Contact:021-54173790

Address:328 WuHe Road, Building #A, 2nd Floor, Minhang, Shanghai 201109, China
Guangzhou Flower's Song Fine Chemical CO,. Ltd

Contact:+86-20-87475199

Address:No.12, Fenghuang 3 Road, Jiulong Industrial Park, Luogang District, Guangzhou. China
SINO Industries Company Limited(expird)

Contact:86-29-85369724

Address:No.111, Jiefang Road, Xi’an, China
EGBERT CORPORATION

Contact:+86 18616952870

Address:Area

Relevant to this article

Metalloporphyrin-Catalyzed Oxidation of Alkanes with Molecular Oxygen in the Presence of Acetaldehyde

Doi:10.1016/0040-4039(95)01708-P
(1995)
Design, synthesis and fungicidal activity studies of 3-ferrocenyl-N-acryloylmorpholine

Doi:10.1016/j.jorganchem.2017.11.015
(2018)
A facile and direct synthesis of alendronate from pyrrolidone

Doi:10.1080/00304940409355395
(2004)
Development of Solvent-Dispersible Coordination Polymer Nanocrystals and Application as Efficient Heterogeneous Catalysts

Doi:10.1021/acs.cgd.6b00502
(2016)
Doi:10.1046/j.1365-2044.2000.01766-9.x
()
Doi:10.1021/ja01114a502
(1953)

Article Doi