Crown Thioether Chemistry. Synthesis and Structural Investigation of 1,5,9-Trithiacyclododecane (Trithia-12-crown-3) and its Copper(II) Chloride Adduct

DOI: 10.1039/DT9880000093

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 93 - 96 (1988)

Update date:2022-08-17

Topics:

Authors:

Rawle, Simon C.

Admans, Gary A.

Cooper, Stephen R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9880000093

1,5,9-Trithiacyclododecane (L¹) (trithia-12-crown-3) adopts a square conformation similar to that of cyclododecane, with one sulphur atom at a corner and two in side positions.Reaction with copper(II) chloride yields an adduct, 1)2Cl2>, that has been characterized by X-ray diffraction.Each copper ion occupies a centre of inversion and has idealized octahedral microsymmetry, with thioether groups at distances of 2.447(1) and 3.050(1) Angstroem.The conformation adopted by the macrocycle is virtually identical to that adopted by the free ligand, which suggests that its conformation is determined by intrinsic factors rather than packing forces.

Full text of DOI:10.1039/DT9880000093

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:3,3'-THIODIPROPANOL

Cas No:10595-09-2

R&D Labs maybe for 10595-09-2

Shantou Baokang Pharmaceutical Co., Ltd.

Contact:+86-754-88873487

Address:5/F B Block Huangshan Bldg Huangshan Rd Shantou
ABA Chemicals (Shanghai) Limited

Contact:021- 5115 9199-232

Address:Suite 18D, #201 Ningxia Road,
Zipont chem(wuhan）Tech co.，Ltd

Contact:+86-27-87587198

Address:wuhan
shijiazhuang alkay chemicals co..ltd(expird)

Contact:86-311-67692035

Address:2601,juntang building,qiaodong district,shijiazhuang
Huangshi Meifeng Chemical Co.,ltd.

Contact:+86-714-6516706

Address:1941-4-3#,Hubin Avenue,Huangshi,Hubei,China

Relevant to this article

Metalloporphyrin-Catalyzed Oxidation of Alkanes with Molecular Oxygen in the Presence of Acetaldehyde

Doi:10.1016/0040-4039(95)01708-P
(1995)
Design, synthesis and fungicidal activity studies of 3-ferrocenyl-N-acryloylmorpholine

Doi:10.1016/j.jorganchem.2017.11.015
(2018)
A facile and direct synthesis of alendronate from pyrrolidone

Doi:10.1080/00304940409355395
(2004)
Development of Solvent-Dispersible Coordination Polymer Nanocrystals and Application as Efficient Heterogeneous Catalysts

Doi:10.1021/acs.cgd.6b00502
(2016)
Doi:10.1046/j.1365-2044.2000.01766-9.x
()
Doi:10.1021/ja01114a502
(1953)

Article Doi