Tin(IV)-catalyzed lactonization of ω-hydroxy trifluoroethyl esters

DOI: 10.1016/S0040-4039(00)73624-0

Source and publish data:

Tetrahedron Letters p. 3515 - 3518 (1993)

Update date:2022-08-11

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Authors:

White White

Green Green

Fleming Fleming

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Article abstract of DOI:10.1016/S0040-4039(00)73624-0

1,1,1-Trifluoroethyl esters of ω-hydroxycarboxylic acids were prepared and their conversion to macrocyclic lactones, including ricinelaidic lactone, was studied in the presence of catalytic quantities of tin(IV) reagents; a mechanism involving exchange of alkoxytrialkyltin species is proposed.

Full text of DOI:10.1016/S0040-4039(00)73624-0

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