Modified borohydride agents, methyltriphenylphosphonium tetrahydroborate; MePh3P+BH4- as a selective and an efficient reducing agent

Article abstract of DOI:10.1080/00397919608004555

MePh₃P⁺BH₄^- is able to reduce aldehydes and ketones to their corresponding alcohols in CH₂Cl₂. Aldehydes are reduced with high selectivity in the presence of ketones. α,β-Unsaturated carbonyl compounds undergo 1,2-reduction and produce their corresponding allylic alcohols in high yields. Carboxylic acid chlorides are also converted to their alcohols with high yields.

Full text of DOI:10.1080/00397919608004555

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Synthetic Communications: An
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Modified Borohydride Agents1a-
d Methyltriphenylphosphonium
Tetrahydroborate; MePh3P+BH4
- as a Selective and An Efficient
Reducing Agent
H. Firouazabadi a & M. Adibi a
a Department of Chemistry , Shiraz University ,
Shiraz, 71454, Iran
Published online: 23 Aug 2006.
To cite this article: H. Firouazabadi & M. Adibi (1996) Modified Borohydride Agents1a-
d Methyltriphenylphosphonium Tetrahydroborate; MePh3P+BH4 - as a Selective and
An Efficient Reducing Agent, Synthetic Communications: An International Journal
for Rapid Communication of Synthetic Organic Chemistry, 26:13, 2429-2441, DOI:
10.1080/00397919608004555
To link to this article: http://dx.doi.org/10.1080/00397919608004555
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