HIGH ORTHO-SELECTIVITY IN THE CHLORINATION OF PHENOLS WITH N-CHLORODIALKYLAMINES IN THE PRESENCE OF SILICA.

DOI: 10.1016/S0040-4039(00)80287-7

Source and publish data:

Tetrahedron Letters p. 1319 - 1322 (1988)

Update date:2022-08-11

Topics:

Authors:

Smith, Keith

Butters, Michael

Nay, Barry

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Article abstract of DOI:10.1016/S0040-4039(00)80287-7

Phenols are readily chlorinated by N-chlorodialkylamines in the presence of silica.Furthermore, this approach allows greater selectivity for mono:di and ortho: para chlorination than is possible with many other approaches.

Full text of DOI:10.1016/S0040-4039(00)80287-7

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