Welcome to LookChem.com Sign In|Join Free

Article Doi

Syntheses, structures, and reactions of alkenyl-dirhodium complexes: coupling μ-methylene and ?-vinyl to allyl; an entry to μ-ethylidene-μ-methylene dirhodium complexes. Crystal structures of 2> and <(C5Me5Rh)2(μ-CH2)(μ-CHMe)Cl2

DOI: 10.1016/0022-328X(90)87256-D

Source and publish data:

Journal of Organometallic Chemistry p. 583 - 599 (1990)

Update date:2022-08-11

Topics:

Authors:

Martinez, JesusMartinez, Jesus

Gill, John B.Gill, John B.

Adams, HarryAdams, Harry

Bailey, Neil A.Bailey, Neil A.

Saez, Isabel M.Saez, Isabel M.

et al.et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(90)87256-D

Reaction of <(C5Me5Rh-μ-CH2)2Cl2> with R'CH=CHMgBr gave the dialkenyl-d-μ-methylenedirhodium complexes <(C5Me5Rh-μ-CH2)2(CH=CHR')2>, (4, R' = H; 5, R' = Me).Coupling of the μ-methylene and the ?-alkenyl occurs very easily: on heating (giving ca. 90percent

View More

Full text of DOI:10.1016/0022-328X(90)87256-D

Products guided by the article

Product name:1-Butene

Cas No:106-98-9

106-98-9

R&D Labs maybe for 106-98-9

Relevant to this article

Hot Product