Syntheses, structures, and reactions of alkenyl-dirhodium complexes: coupling μ-methylene and ?-vinyl to allyl; an entry to μ-ethylidene-μ-methylene dirhodium complexes. Crystal structures of 2> and <(C5Me5Rh)2(μ-CH2)(μ-CHMe)Cl2

DOI: 10.1016/0022-328X(90)87256-D

Source and publish data:

Journal of Organometallic Chemistry p. 583 - 599 (1990)

Update date:2022-08-11

Topics:

Authors:

Martinez, Jesus

Gill, John B.

Adams, Harry

Bailey, Neil A.

Saez, Isabel M.

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(90)87256-D

Reaction of <(C5Me5Rh-μ-CH2)2Cl2> with R'CH=CHMgBr gave the dialkenyl-d-μ-methylenedirhodium complexes <(C5Me5Rh-μ-CH2)2(CH=CHR')2>, (4, R' = H; 5, R' = Me).Coupling of the μ-methylene and the ?-alkenyl occurs very easily: on heating (giving ca. 90percent

Full text of DOI:10.1016/0022-328X(90)87256-D

Products guided by the article

Product name:1-Butene

Cas No:106-98-9

R&D Labs maybe for 106-98-9

Binzhou Holly Pharmaceutical Co.,Ltd.

Contact:74517

Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China
Hangzhou TJM Chemical Trade Co., Ltd

Contact:86-571-88223276 86-13388481653

Address:2221#,Boyuexuan,1860# Binsheng Road,Binjiang District, Hangzhou CityZhejiang Province, 310051, P. R. China
Nanjing Ruizhi Industry & Technologh Co.，Ltd.

Contact:+86-25-86808110

Address:441-4-A5,NO.12 Longzang Avenue,Yuhuatai District,210039,Nanjing
Jiaxing Taixin Pharmaceutical Chemical Co., Ltd

Contact:0573-82613601

Address:Chemical Park, Jiaxing, Zhejiang, China
Guangzhou Reachin Chemical Co., Ltd

Contact:+86-20-37087379 ext.604

Address:A122C-1, Tianyuan Plaza, 401 Tianyuan Rd., Tianhe, Guangzhou, China

Relevant to this article

STRUCTURES OF ISOMERIC ANIONS IN THE GAS PHASE: ARYLLALLYL AND ARYLCYCLOPROPYL ANIONS.

Doi:10.1021/ja00316a003
(1984)
The design, synthesis and evaluation of selenium-containing 4-anilinoquinazoline hybrids as anticancer agents and a study of their mechanism

Doi:10.1039/c8ob00875b
(2018)
Synthesis and Evaluation of Nicotinic Acid Derived Tetrazines for Bioorthogonal Labeling

Doi:10.1055/s-0034-1380721
(2015)
Ultraviolet Photoelectron Spectrum of the Phenoxy Radical

Doi:10.1021/ja00544a050
(1980)
Zinc(II) Complexes of N,N-Di(2-picolyl)hydrazones

Doi:10.1002/ejic.201601066
(2016)
Vinyl ethers with isothiocyanate group: XIX. Reaction with dicarboxylic acids: A simple route to N,N′-bis[(2-vinyloxy)ethyl]amides

Doi:10.1023/A:1020374601246
(2002)

Article Doi