Oxidative Addition of Vinyl Acetate to Ruthenium (0) Involving Carbon Oxygen Bond Cleavage Forming a Novel Vinyl(aceto)tris(triethylphosphine)ruthenium(II)

DOI: 10.1246/cl.1987.1287

Source and publish data:

Chemistry Letters p. 1287 - 1290 (1987)

Update date:2022-08-11

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Authors:

Komiya, Sanshiro

Suzuki, Jun-ichi

Miki, Kunio

Kasai, Nobutami

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Article abstract of DOI:10.1246/cl.1987.1287

Vinyl acetate oxidatively adds to (1,5-cyclooctadiene)(1,3,5-cyclooctatriene)ruthenium(0) in the presence of triethylphosphine to give mer-vinyl(acetato)tris(triethylphosphine)ruthenium(II) at 50 deg C in hexane, which has been unequivocally characterized by 1H, (31)P, and (13)C NMR, IR, elemental analysis, and X-ray structure analysis.

Full text of DOI:10.1246/cl.1987.1287

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