Journal of Physical Chemistry p. 5679 - 5684 (1986)
Update date:2022-08-28
Topics:
Guckert, Joseph R.
Carr, Robert W.
The infrared multiple-photon photolysis of trans-2-butene was investigated at five CO2 wavelenghts from 942 to 1031 cm-1 and at conversions from a few percent to approximately 95 percent.The reaction products at 50 mTorr and fluences of approximately 125 J/cm2 were cis-2-butene, ethylene, ethane, propylene, propyne, 1,3-butadiene, 1-butene and 2-butyne.Relative product yields of cis-2-butene and propyne varied significantly with both wavelenght and conversion.The results of an investigation of the observed product selectivity are presented.
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