ACS Catalysis p. 7338 - 7342 (2015)
Update date:2022-08-16
Topics:
Escobar, Manuel A.
Trofymchuk, Oleksandra S.
Rodriguez, Barbara E.
Lopez-Lira, Claudia
Tapia, Ricardo
Daniliuc, Constantin
Berke, Heinz
Nachtigall, Fabiane M.
Santos, Leonardo S.
Rojas, Rene S.
A cationic methallyl 2-pyridine-4,7-dimethoxybenzimidazole (L1) nickel precatalyst is highly selective in ethene dimerizations to 1-butene. The same catalyst isomerizes 1-butene and 1-octene to internal olefins. Co-catalytic additives of B(C6F5)3 or BF3·OEt2 coordinate to the catalyst and increase the reaction rates of ethene dimerization. ESI-MS was applied identifying a [L1NiH]+ cation as the catalytically active species.
View MoreChangsha Goomoo Chemical Technology Co.Ltd
Contact:+86-731-82197655
Address:No.649,Chezhan Rd.(N),Changsha,Hunan,China
Angelisun(Chongqing) Pharmaceutical Co., LTD.
Contact:+86-23-68030926-816
Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
Suzhou Wedo Chemicals Co., Ltd.
Contact:86 512 58100425
Address:Zonger Road, DongSha Industry Park , Zhangjiagang, Jiangsu, China
Changzhou LanXu Chemical Co.,ltd.(expird)
Contact:86-0519-86330911,13656129734,15261186386
Address:Room 524, Depart.Chemical, Changzhou Science and Eductaion town, Jiangsu, China;Factory: Haian Fine Chemical Industry Park,Nantong,Jiangsu,China
A.M FOOD CHEMICAL CO., LIMITED
Contact:86-531-87100375
Address:20Floor，Bblock，1Building，pharma-valley，Jinan，China
Doi:10.1039/j39710001818
(1971)Doi:10.1039/b717269a
(2008)Doi:10.1246/bcsj.70.761
(1997)Doi:10.1111/j.1753-6405.2001.tb01832.x
(1956)Doi:10.1007/BF00941711
()Doi:10.1016/j.molstruc.2019.04.100
(2019)
