Journal of the Chemical Society. Chemical communications p. 1593 - 1594 (1988)
Update date:2022-08-11
Topics:
Hayakawa, Takashi
Tsunoda, Tatsuo
Orita, Hideo
Kameyama, Tetsuya
Ueda, Minoru
et al.
Partial oxidation of alkenes by oxygen species transported electrochemically on a scheelite-type molybdate catalyst via yttria-stabilized zirconia at 450-475 deg C has revealed that oxygen species transported through the bulk of the catalyst insert into an allylic intermediate to form the oxygenated product, while oxygen species chemisorbed on the catalyst surface from the gas phase accelerate deep oxidation.
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