A Solid Electrolyte-aided Study of Alkene Oxidation on a Molybdate Catalyst having the Scheelite Structure

DOI: 10.1039/c39880001593

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1593 - 1594 (1988)

Update date:2022-08-11

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Authors:

Hayakawa, Takashi

Tsunoda, Tatsuo

Orita, Hideo

Kameyama, Tetsuya

Ueda, Minoru

et al. et al.

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Article abstract of DOI:10.1039/c39880001593

Partial oxidation of alkenes by oxygen species transported electrochemically on a scheelite-type molybdate catalyst via yttria-stabilized zirconia at 450-475 deg C has revealed that oxygen species transported through the bulk of the catalyst insert into an allylic intermediate to form the oxygenated product, while oxygen species chemisorbed on the catalyst surface from the gas phase accelerate deep oxidation.

Full text of DOI:10.1039/c39880001593

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