RADICAL ANIONS OF NITROSOIMIDAZOLES: PUTATIVE INTERMEDIATES IN THE MECHANISM OF ACTION OF NITROIMIDAZOLE ANTIBIOTICS

DOI: 10.1016/S0040-4039(00)94737-3

Source and publish data:

Tetrahedron Letters p. 3221 - 3224 (1990)

Update date:2022-08-10

Topics:

Authors:

Symons, Martyn C. R.

Bowman, W. Russell

Taylor, Peter F.

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Article abstract of DOI:10.1016/S0040-4039(00)94737-3

The radical anions of 1-methyl-4-phenyl-5-nitrosoimidazole and 5-phenyl-4-nitrosoimidazole have been detected using temperature resolved e.s.r spectroscopic techniques and are proposed as putative intermediates in the oxidation of thiols to disulphides by the nitrosoimidazoles.

Full text of DOI:10.1016/S0040-4039(00)94737-3

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