Journal of the Chemical Society. Chemical communications p. 329 - 330 (1995)
Update date:2022-08-30
Topics:
Inoue, Tomoya
Tomishige, Keiichi
Iwasawa, Yasuhiro
The Pt-Sn/SiO2 catalysts prepared by selective bimetallic CVD reaction of SnMe4 with Pt particles on SiO2, characterized by EXAFS (extended X-ray absorption fine structure), yield acrylonitrile from NO + propene and methacrylonitrile from NO + isobutene and NO + isobutane with good selectivities, typically 70-93percent, in contrast to negligible activity and selectivity (about one order of magnitude lower) with the monometallic Pt/SiO2 catalyst.
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