Nucleophilic Substitution Reactions at Chloro-Substituted Ozonides and at a Chlorinated Dimeric Peroxide

Article abstract of DOI:10.1021/jo00129a055

Reactions of substituted 3-chloro- (2a-4a) and 3,5-dichloro-1,2,4-trioxolanes (9a, 10a) with AgBF4 in the presence of LiF gave the corresponding fluoro-substituted ozonides (2b - 4b and 9b and 10b).Substitutions of some of these chlorinated ozonides by the methoxy and by the acetoxy groups, and of 3,6-dichloro-3,6-dimethyl-1,2,4,5-tetroxane (22a) with the acetoxy group have been achieved too.