Mononuclear Tetracarbonylrhodate Rh(CO)4(1-). A New Aspect of Syngas Conversion into Ethylene Glycol

DOI: 10.1039/c39860000227

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 227 - 228 (1986)

Update date:2022-08-29

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Authors:

Watanabe, Eiichi

Murayama, Kenji

Hara, Yoshinori

Kobayashi, Yoshimitsu

Wada, Keisuke

Onoda, Takeru

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Article abstract of DOI:10.1039/c39860000227

Syngas treatment of Rh4(CO)12 in 1-methylpyrrolidin-2-one gives a colourless solution of mononuclear tetracarbonylrhodate, Rh(CO)4(1-), which is closely related to the active catalytic species that produces ethylene glycol.

Full text of DOI:10.1039/c39860000227

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