Chemistry Letters p. 1274 - 1275 (2007)
Update date:2022-08-17
Topics:
Feng, Jian
Wang, Jinbo
Zhou, Yafen
Fu, Haiyan
Chen, Hua
Li, Xianjun
Under mild reaction conditions (170°C, 3 MPa), glycerol is hydrogenolyzed to 1,2-propanediol with very high selectivity at high conversion using Ru/TiO2 as catalyst in basic aqueous solution. The base aids the initial dehydrogenation of glycerol to glyceraldehyde and promotes the dehydration of glyceraldehyde to 2-hydroxyacrolein. Copyright
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