Preparation of Thionylimide Complexes of Titanium, Zirconium, and Hafnium. Crystal Structure of

DOI: 10.1039/DT9890001815

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1815 - 1818 (1989)

Update date:2022-08-11

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Authors:

Plenio, Herbert

Roesky, Herbert W.

Edelmannn, Frank T.

Noltemeyer, Mathias

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Article abstract of DOI:10.1039/DT9890001815

The compounds , (Zr(cp)(η-C5Me5)2(NSO)2>, , and (Hf(cp)(η-C5Me5)(NSO)2> (cp = η-C5H5) have been prepared from corresponding metal halides and K(NSO).The transition-metal-bonded NSO groups can be transformed into NSNSiMe3 by reaction with Li, giving .A compound containing three NSO ligands has been prepared from the reaction of SnMe3(NSO) and .The X-ray crystal structure of reveals a pseudo-tetrahedral co-ordination of the metal, with two nitrogen-bonded NSO ligands forming a nearly planar Zr(NSO)2 unit.

Full text of DOI:10.1039/DT9890001815

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