Preparation of Thionylimide Complexes of Titanium, Zirconium, and Hafnium. Crystal Structure of

DOI: 10.1039/DT9890001815

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1815 - 1818 (1989)

Update date:2022-08-11

Topics:

Authors:

Plenio, Herbert

Roesky, Herbert W.

Edelmannn, Frank T.

Noltemeyer, Mathias

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9890001815

The compounds , (Zr(cp)(η-C5Me5)2(NSO)2>, , and (Hf(cp)(η-C5Me5)(NSO)2> (cp = η-C5H5) have been prepared from corresponding metal halides and K(NSO).The transition-metal-bonded NSO groups can be transformed into NSNSiMe3 by reaction with Li, giving .A compound containing three NSO ligands has been prepared from the reaction of SnMe3(NSO) and .The X-ray crystal structure of reveals a pseudo-tetrahedral co-ordination of the metal, with two nitrogen-bonded NSO ligands forming a nearly planar Zr(NSO)2 unit.

Full text of DOI:10.1039/DT9890001815

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Hexamethyldisiloxane

Cas No:107-46-0

R&D Labs maybe for 107-46-0

Anqing World Chemical Co., Ltd.

Contact:+86-556-5800026

Address:Daguan Economic Development Zone of circular economy industrial park Anqing City Anhui province
Suns Chemical Sdn Bhd

Contact:0086 371 65711996

Address:Jalan 4/3, Kawasan Perindustrian Serendah, 48000 Rawang,
Anhui Hope-Chem Co., Ltd.

Contact:86-551-63540590

Address:No 1388 Furong Rd., Hefei, Anhui, China
SINFACHEM LIMITED

Contact:86-25-84683399

Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002
ANGCHEN BRIGHTCHEM CO., LTD

website:http://www.angchenchem.com

Contact:+86-510-88302099 82327577

Address:Rm. 404/405, Floor 4th, No. 983 FengXiang Road, Wuxi, China

Relevant to this article

Facile synthesis of tin oxide nanoparticles stabilized by dendritic polymers

Doi:10.1021/ja056902n
(2006)
Graphitic carbon nitride (g-C₃N₄)/graphite nanocomposite as an extraordinarily sensitive sensor for sub-micromolar detection of oxalic acid in biological samples

Doi:10.1039/c9ra00982e
(2019)
A Double Prodrug with Improved Membrane Permeability over the Parent Chelator HBED Provides Superior Cytoprotection against Hydrogen Peroxide

Doi:10.1002/cmdc.201600197
(2016)
COMPARISONS OF VARIOUS BIOLOGICAL ACTIVITIES OF STEREOISOMERS OF METHYL JASMONATE

Doi:10.1016/0031-9422(92)80243-8
(1992)
Development of a novel protocol for chemoselective deprotection of N/O-benzyloxycarbonyl (Cbz) at ambient temperature

Doi:10.1007/s00706-018-2276-x
(2018)
"Structured Nuclei" of 4-(Octadecyloxy)benzoic Acid Monolayer for Induced Nucleation of 4-Hydroxybenzoic Acid Monohydrate As Determined by Grazing Incidence X-ray Diffraction on the Aqueous Solution

Doi:10.1021/j100016a046
(1995)

Article Doi