New synthesis of tert-butyl peroxycarboxylates

Article abstract of DOI:10.1134/S1070428006040026

tert-Butyl peroxyacetate, tert-butyl peroxybutyrate, tert-butyl phenylperoxyacetate, and tert-butyl peroxyundecanoate were obtained in nearly quantitative yields by the esterification of the corresponding carboxylic acids with tert-butyl hydroperoxide in the presence of trifluoroacetic anhydride and pyridine in nonaqueous medium at 0-5°C. No tert-butyl peroxytrifluoroacetate was formed as a by-product during the process. A possible reaction mechanism is discussed. Pleiades Publishing, Inc., 2006.

Full text of DOI:10.1134/S1070428006040026

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