Journal of the Chemical Society - Faraday Transactions p. 3591 - 3598 (1992)
Update date:2022-08-11
Topics:
Juszczyk, Wojciech
Marczewski, Marek
The physico-chemical and catalytic properties of alumina exposed to ZrCl4 vapour have been studied.It was found that ZrCl4 reacts with both basic surface OH groups and exposed O2- ions forming Lewis superacid centres as well as Broensted acid sites.The mechanism of n-pentane low-temperature isomerization involving H- abstraction from the alkane has been postulated.
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