Tetrahedron p. 973 - 978 (1994)
Update date:2022-08-25
Topics:
Holleben, Maria Luiza A. von
Zucolotto, Monica
Zini, Claudia A.
Oliveira, Eduardo R.
A selective hydrogenation of carbon-carbon double bond of α,β-unsaturated ketones are obtained when a mixture of limonene, α,β-unsaturated ketone and 10percent Pd/C is refluxed with vigorous stirring for 15-45 min.The best results are obtained when a molar ratio limonene:α,β-unsaturated ketone of 3:1 and 4 molar percent palladium/ketone are used.The stereoselectivity is similar to the results obtained when H2 and Pd/C have been used in neutral solvent.
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Doi:10.1002/psc.2662
(2014)Doi:10.1021/acs.joc.8b01379
(2018)Doi:10.1016/j.mcat.2020.111276
(2021)Doi:10.1039/c5dt04149j
(2016)Doi:10.1039/b008339i
(2001)Doi:10.1016/0040-4039(94)88327-0
(1994)
