The addition of halogenocarbons to alkenes in the presence of and related complexes

DOI: 10.1016/0022-328X(90)85248-W

Source and publish data:

Journal of Organometallic Chemistry p. 229 - 239 (1990)

Update date:2022-08-10

Topics:

Authors:

Davis, Reg

Durrant, Jim L. A.

Khazal, Nasser M. S.

Bitterwolf, Thomas E.

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Article abstract of DOI:10.1016/0022-328X(90)85248-W

A kinetic study has been made of the addition of halogenocarbons to alkenes in the presence of (I).The results, together with the results of cross-over addition reactions of a halogenocarbon mixture and cross-over studies on catalyst mixtures of I and (II) have been interpreted in terms of a mechanism which involves catalysis by an intact dinuclear species, probably , but which also involves free radical intermediates.

Full text of DOI:10.1016/0022-328X(90)85248-W

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