Journal of the Chemical Society. Perkin transactions II p. 1827 - 1832 (1985)
Update date:2022-08-25
Topics:
Gunji, Tomokazu
Hirano, Masao
Morimoto, Takashi
The kinetics of oxidative cleavage of glycols by obalt(III) acetate in acetic acid have been studied.The substrates examined include cis- and trans-cyclopentane- and cyclohexane-1,2-diols and their mono- and dimethyl derivatives.The rates were first-order in both cobalt(III)acetate and substrate in all cases.In the oxidation of five-membered ring diols, cis-diols were generally oxidized faster than the trans-isomers.Complex results were obtained in the case of six-membered ring diols.Thermodynamic parameters were calculated for all the substrates.A mechanism involving a bidente complex of cobalt(III) acetate dimer and glycol is sugge sted, except for the case of trans-cyclopentane-1,2-diols, for which a monodentate intermediate is proposed.
View MoreHangzhou Neway Chemicals Co., Ltd.
Contact:+86-571-85095566
Address:Room 803, Qinglian Bldg, No 139 Qingchun Road, Hangzhou, Zhejiang China
Liaoning Yufeng Chemical Co.,Ltd.
Contact:86-0419-3418888
Address:The metallurgical industrial zone,shoushan town, Liaoyang, Liaoning, China
Wuhan Jadechem International Trade Co.,Ltd.
website:http://www.jadechem-intl.com
Contact:+86-27-83527060
Address:Room 502,Building C11,Software new city No.8,Huacheng Avenue,East Lake High-tech development zone,Wuhan,Hubei,China
Geen Chemical Technology Co., Ltd
Contact:86-769-21660847
Address:1408, Yingfeng Commercial Center, Nancheng District
Contact:86-511-85210668 0511-85210668, 85210818, 85210898
Address:Yihai Garden E-902,NO.99 Daxi RD., Zhenjiang Jiiangsu ,China
Doi:10.1016/j.tetlet.2008.05.048
(2008)Doi:10.1021/acs.organomet.8b00267
(2018)Doi:10.1016/0040-4039(95)02281-3
(1996)Doi:10.1023/A:1013816422004
(2001)Doi:10.1007/s11172-015-0951-1
(2015)Doi:10.1007/s11172-017-1995-1
(2017)
