Indole as a tool in synthesis. Indolenine approach to 4,5-epoxy-10-normorphinans

DOI: 10.1016/0040-4020(96)00378-X

Source and publish data:

Tetrahedron p. 8209 - 8222 (1996)

Update date:2022-08-11

Topics:

Authors:

Sapi, Janos

Dridi, Seloua

Laronze, Jacqueline

Sigaut, Francoise

Patigny, Dominique

Laronze, Jean-Yves

Levy, Jean

Toupet, Loic

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Article abstract of DOI:10.1016/0040-4020(96)00378-X

The 4,5-epoxy-10-normorphinans 2a and 2b featuring the morphine skeleton lacking the Bring were synthesized using the "nitrous acid deamination" of indolenines as the key step. Thus, indolenines 13 and 15 were prepared by Fischer synthesis from the corres

Full text of DOI:10.1016/0040-4020(96)00378-X

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