Studies directed towards the synthesis of immunosuppressive agent FK 506: Synthesis of C-20 to C-27 moiety

DOI: 10.1016/S0040-4039(00)88828-0

Source and publish data:

Tetrahedron Letters p. 1443 - 1446 (1990)

Update date:2022-08-11

Topics:

Authors:

Rao Rao

Chakraborty

Purandare

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Article abstract of DOI:10.1016/S0040-4039(00)88828-0

Regioselective ring opening of (2S,3R)-epoxide of 4-benzyloxy-cis-2-buten-1-ol with Me₂CuLi and diastereofacial selective aldol reaction with enolsilane are the key steps involved in the stereospecific construction of '2-methyl-1,3-diol' backbo

Full text of DOI:10.1016/S0040-4039(00)88828-0

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Product name:(2R,3S)-4-(benzyloxy)-2-methylbutane-1,3-diol

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