Chemical and Pharmaceutical Bulletin p. 445 - 446 (2000)
Update date:2022-08-30
Topics:
Tohma, Hirofumi
Takizawa, Shinobu
Morioka, Hironori
Maegawa, Tomohiro
Kita, Yasuyuki
A new catalytic asymmetric oxidation of sulfides to sulfoxides in water using the hypervalent iodine(V) reagent iodoxybenzene (PhIO2) has been developed. This methodology is distinctly different from the previously reported use of cyclodextrins or biological catalysts and provides a new route to asymmetric sulfoxidation in water.
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