
Journal of Organometallic Chemistry p. 1 - 13 (1992)
Update date:2022-08-11
Topics:
Markies, Peter R.
Schat, Gerrit
Akkerman, Otto S.
Bickelhaupt, F.
Spek, Anthony L.
The complexation behavior of diphenylzinc with a series of mono-, di- and tri-coordinating ethers has been investigated.Two stable crystalline 1:1 adducts, with ethyleneglycol dimethyl ether (glyme) (1) and diethyleneglycol dimethyl ether (diglyme) (2) were isolated and characterized by an X-ray diffraction study.Complex 1 has a normal tetra-coordinated zinc atom; 2 represents the first example of a complex penta-coordinated diorganozinc compound, and has a rather unusual geometry.
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