Studies on the Oxidation of Alcohols Employing t-Butyl Hydroperoxide (TBHP) and Fe(III) Catalysts.

DOI: 10.1016/S0040-4039(00)76940-1

Source and publish data:

Tetrahedron Letters p. 4681 - 4684 (1994)

Update date:2022-08-11

Topics:

Authors:

Barton, Derek H. R.

Beviere, Stephane D.

Chabot, Beatrice M.

Chavasiri, Warinthorn

Taylor, Dennis K.

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Article abstract of DOI:10.1016/S0040-4039(00)76940-1

New methodology for the oxidation of alcohols to ketones in good yield utilizing catalytic amounts of Fe^III salts and TBHP as the oxidant is highlighted.Competition between alcohol and hydrocarbon oxidation has been clearly demonstrated.The "normal" Gif-type solvent system (pyridine/ acetic acid) can be replaced by the alcohol itself.

Full text of DOI:10.1016/S0040-4039(00)76940-1

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