Journal of Organometallic Chemistry p. 1 - 14 (1987)
Update date:2022-08-05
Topics:
Tellier, Frederique
Sauvetre, Raymond
Normant, Jean-F.
Several fluoroenynes have been prepared by palladium-catalyzed cross-coupling reactions.Cycloaddition reactions of these enynes give substituted cyclobutanes, whereas treatment with sulfuric acid leads to α-fluoro-α-allenic acid fluorides, lactones, α-fluoro-β-diketones or cyclic α-fluoroenones, according to the nature of the starting enyne.The cyclisation process is discussed.
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