Coupling and carbonylation of iodoaromatics and terminal alkynes or alkynols catalyzed by a dimeric palladium hydroxide

DOI: 10.1055/s-1994-25660

Source and publish data:

Synthesis p. 1149 - 1151 (1994)

Update date:2022-08-18

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Authors:

Delaude Delaude

Masdeu Masdeu

Alper Alper

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Article abstract of DOI:10.1055/s-1994-25660

The palladium(II) complex [(Ph₃P)Pd(Ph)(μ-OH)]₂ is an effective catalyst for the coupling aud carbonylation of alkynes and iodoarenes to give acetylenic ketones in 63-94% yields. Acetylenic hydroxy ketones were formed using secondary or tertiary alkynols as reactants.

Full text of DOI:10.1055/s-1994-25660

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