
Tetrahedron Letters p. 3387 - 3390 (1997)
Update date:2022-08-11
Topics:
Foulon, Frederique
Fixari, Bernard
Picq, Dominique
Le Perchec, Pierre
Hexabutylguanidinium chloride (0.5 molar %) efficiently decomposes alkyl chloroformates into chlorides, with low alkenes formation, via a S(N)2 mechanism as demonstrated from substituents effects and asymmetric chloride synthesis.
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(1997)