Novel, Direct Amination of Anthraquinone by Rhodium(I) Complexes

DOI: 10.1039/c39800001036

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1036 - 1037 (1980)

Update date:2022-08-16

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Authors:

Mita, Katsuhisa

Yamagishi, Takamichi

Hida, Mitsuhiko

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Article abstract of DOI:10.1039/c39800001036

In the presence of certain rhodium(I) complexes, anthraquinone was found to react with amines to give the 1-alkylaminoanthraquinones, along with small amounts of the 1,4-bis(alkylamino)anthraquinones; this direct amination characteristically occurs only at the α-position of anthraquinone.

Full text of DOI:10.1039/c39800001036

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