An Improved Method for Stereoselective Synthesis of (E)-Alkenes via Alkenyldialkylboranes

DOI: 10.1246/bcsj.59.3985

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3985 - 3987 (1986)

Update date:2022-08-11

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Authors:

Hoshi, Masayuki

Masuda, Yuzuru

Arase, Akira

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Article abstract of DOI:10.1246/bcsj.59.3985

Successive treatments of alkenyldialkylboranes, formed by the reaction of alkynes and sterically hindered dialkylboranes, with alkyllithium and benzenesulfenyl chloride afforded highly pure (E)-alkenes in good or excellent yields.

Full text of DOI:10.1246/bcsj.59.3985

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Product name:Cyclohexane, (3,3-dimethyl-1-butenyl)-, (E)-

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