A DIRECTED METALATION ROUTE TO THE ZWITTERIONIC INDOLE ALKALOIDS. SYNTHESES OF INDOLOQUINOLIZINE, FLAVOPEREIRINE, FLAVOCARPINE, AND DIHYDROFLAVOPEREIRINE

DOI: 10.1016/S0040-4039(00)96702-9

Source and publish data:

Tetrahedron Letters p. 5259 - 5262 (1987)

Update date:2022-08-04

Topics:

Authors:

Gribble, Gordon W.

Johnson, David A.

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Article abstract of DOI:10.1016/S0040-4039(00)96702-9

A protocol involving beta-lithiation of 2-(2-pyridinyl)indoles (4->5) and subsequent reaction with bromoacetaldehyde or oxirane has led to syntheses of the alkaloids indolo<2,3-a>quinolizine (1), flavopereirine (2), flavocarpine (21), and dihydroflavopere

Full text of DOI:10.1016/S0040-4039(00)96702-9

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