Polyenolates of unsaturated carboxylic acids in synthesis. Synthesis of unsaturated α-amino acids and γ-hydrazino acids

Article abstract of DOI:10.1080/00397919108021773

Regioselective reaction of lithium diene- and triene-diolates 1 and 2 with o-diphenylphosphinyl hydroxylamine affords unsaturated α-amino acids 3 and 4. Addition to DEAD leads selectively to γ-hydrazino unsaturated acids 5 and 6.

Full text of DOI:10.1080/00397919108021773

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Polyenolates of Unsaturated
Carboxylic Acids in
Synthesis. Synthesis of
Unsaturated α-Amino Acids
and β-Hydrazing Acids
M. J. Aurell a , S. Gil a , P. V. Martinez a , M.
Parra a , A. Tortajada a & R. Mestres a
a Department de Química Orgànica, Facultat de
Química , Universitat de València , Burjassot,
València, Spain
Published online: 23 Sep 2006.
To cite this article: M. J. Aurell , S. Gil , P. V. Martinez , M. Parra , A. Tortajada
& R. Mestres (1991) Polyenolates of Unsaturated Carboxylic Acids in Synthesis.
Synthesis of Unsaturated α-Amino Acids and β-Hydrazing Acids, Synthetic
Communications: An International Journal for Rapid Communication of Synthetic
Organic Chemistry, 21:18-19, 1833-1839, DOI: 10.1080/00397919108021773
To link to this article: http://dx.doi.org/10.1080/00397919108021773
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