Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 3033 - 3039 (1986)
Update date:2022-08-10
Topics:
Puttock, Simon J.
Rochester, Colin H.
Broensted-acidic hydroxy groups on the surface of vanadyl pyrophosphate act as catalytically active sites for the isomerisation of but-1-ene to but-2-enes.Progressive poisoning of the reaction is attributed to the tormation of alkyl species, possibly alkoxy groups, on the (VO)2P2O7 surface.Adsorbed alkyl groups also result from buta-1,3-diene adsorption.Furan adsorbs on (VO)2P2O7 through coordinative interactions with Lewis-acidic surface sites.The presence of oxygen promotes the oxidation of furan to maleic anhydride.
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