Journal of the Chemical Society - Faraday Transactions p. 3247 - 3252 (1990)
Update date:2022-08-17
Topics:
Bennett, John E.
The kinetics of reactions of t-butylperoxyl radicals in aqueous solution have been measured using electron paramagnetic resonance, ultraviolet absorption spectroscopy and gas chromatography.The rate constants for the overall self-reaction, the separate terminating and non-terminating reactions are very similar to those observed in non-polar solvents and the gas phase.The t-butoxy radicals, formed by the non-terminating reaction, can either undergo scission, which leads to methylperoxyl radicals, or react with further t-butyl hydroperoxide to regenerate t-butylperoxy radicals.The cross-termination reaction between methylperoxyl and t-butylperoxyl radicals is an important route in the overall termination sequence.The propagation reaction occurs significantly only at high concentrations of t-butyl hydroperoxide, (
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